Step-growth kinetics#
The Carothers equation relating the number-average degree of polymerization to the extent of reaction, and its generalization to a stoichiometric imbalance between functional groups.
Also the Flory-Stockmayer and Carothers gel points of branching polymerizations.
Flory-Stockmayer gelation: the gel point of a branching polymerization
Flory-Stockmayer gelation: the gel point of a branching polymerization