Rate theory#

Predicting a rate constant from molecular properties: hard-sphere collision theory, Smoluchowski’s diffusion-controlled encounter rate, Eyring’s transition-state theory, and the Lindemann-Hinshelwood pressure falloff of unimolecular rate constants.

Trautz-Lewis collision theory: rate constants from molecular collisions

Trautz-Lewis collision theory: rate constants from molecular collisions

Smoluchowski’s diffusion-limited reaction rate

Smoluchowski's diffusion-limited reaction rate

Eyring’s transition-state theory: activation enthalpy and entropy

Eyring's transition-state theory: activation enthalpy and entropy

Lindemann-Hinshelwood falloff of a unimolecular rate constant

Lindemann-Hinshelwood falloff of a unimolecular rate constant