Rate theory#

Predicting a rate constant from molecular properties: hard-sphere collision theory, Smoluchowski’s diffusion-controlled encounter rate, and Eyring’s transition-state theory.

Trautz-Lewis collision theory: rate constants from molecular collisions

Trautz-Lewis collision theory: rate constants from molecular collisions

Smoluchowski’s diffusion-limited reaction rate

Smoluchowski's diffusion-limited reaction rate

Eyring’s transition-state theory: activation enthalpy and entropy

Eyring's transition-state theory: activation enthalpy and entropy